\(m_{không.tan}=m_{Cu}=2\left(g\right)\\ \Rightarrow m_{Al,Fe}=10,3-2=8,3\left(g\right)\\ Đặt:a=n_{Al}\left(mol\right);b=n_{Fe}\left(mol\right)\left(a,b>0\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=8,3\\1,5.22,4a+22,4b=5,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \Rightarrow\%m_{Cu}=\dfrac{2}{10,3}.100\approx19,417\%\\ \%m_{Fe}=\dfrac{56.0,1}{10,3}.100\approx54,369\%\\ \Rightarrow\%m_{Al}\approx26,214\%\)

\(n_{H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(\Rightarrow n_{HCl}=2\cdot n_{H_2}=2\cdot0.3=0.6\left(mol\right)\)

BTKL : 

\(m_{Muối}=m_{hh}+m_{HCl}-m_{H_2}=18.6+0.6\cdot36.5-0.3\cdot2=39.9\left(g\right)\)

Cu ko tác dụng được với H2SO4 loãng 

=> khí H2 sinh ra là do Zn tác dụng hết với H2SO4

\(Zn+H_2SO_4->ZnSO_4+H_2\)

0.2.......................................0,2

n H2 = 4,48 : 22,4 = 0,2 mol 

m Zn = 0,2 . 65 =13 g 

m Cu = 25 - 13 =12 g 

Fe + 2HCl -->. FeCl2 + H2

0,15-----0,3
Cu không pứ với HCl
nH2 =3,36\22,4= 0,15 mol
=> nFe = 0,15 mol
=>mFe = 0,15.56 = 8,4 g
=>mCu=10-8,4=1,6g

=>mHCl=0,3.98=29,4g

=>mddHCl=80,55g

\(n_{H_2}=\dfrac{0,784}{22,4}=0,035\left(mol\right)\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=1,39\\1,5a+b=0,035\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,01\\b=0,02\end{matrix}\right.\\ \Rightarrow\%m_{Al}=\dfrac{0,01.27}{1,39}.100=37,53\%\\ \Rightarrow\%m_{Fe}=100\%-37,53\%=62,47\%\)

1)

Fe + 2HCl --> FeCl₂ + H₂

Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

2)

- Xét TN1:

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

         0,15<------------------0,15

=> m_Fe = 0,15.56 = 8,4 (g)

\(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{8,4}{14,8}.100\%=56,757\%\\\%m_{Cu}=100\%-56,757\%=43,243\%\end{matrix}\right.\)

3) 

- Xét TN2:

\(n_{Cu}=\dfrac{29,6.43,243\%}{64}=0,2\left(mol\right)\)

PTHH: Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

            0,2-------------------------->0,2

=> V = 0,2.22,4 = 4,48 (l)

- Cu không tác dụng được với dd H₂SO₄ loãng.

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{Zn}=n_{H_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Zn}=\dfrac{0,1.65}{10,5}.100\approx61,905\%\\ \Rightarrow\%m_{Cu}\approx38,095\%\)